Self-Assembly of a 1D Hydrogen-Bonded Polymer from a Hexamethyltetraaza Macrocyclic Nickel(II) Complex and Isophthalic Acid

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Self-assembly of a 1D hydrogen-bonded polymer from a hexamethyltetraaza macrocyclic nickel(II) complex and isophthalic acid.

The compound [Ni(L)(isoph)₂][Ni(L)]·8H₂O (1; L = C-meso-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane; H₂-isoph = isophthalic acid) has been synthesized and structurally characterized. Complex 1 exhibits a geometrically symmetric core with a {4/6} coordination number set. The coordination environment around the Ni(1) ion is a distorted octahedron, while the geometry around the fou...

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ژورنال

عنوان ژورنال: Molecules

سال: 2013

ISSN: 1420-3049

DOI: 10.3390/molecules18066608